28 research outputs found

    Polarization-Based Illumination Detection for Coherent Augmented Reality Scene Rendering in Dynamic Environments

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    A virtual object that is integrated into the real world in a perceptually coherent manner using the physical illumination information in the current environment is still under development. Several researchers investigated the problem producing a high-quality result; however, pre-computation and offline availability of resources were the essential assumption upon which the system relied. In this paper, we propose a novel and robust approach to identifying the incident light in the scene using the polarization properties of the light wave and using this information to produce a visually coherent augmented reality within a dynamic environment. This approach is part of a complete system which has three simultaneous components that run in real-time: (i) the detection of the incident light angle, (ii) the estimation of the reflected light, and (iii) the creation of the shading properties which are required to provide any virtual object with the detected lighting, reflected shadows, and adequate materials. Finally, the system performance is analyzed where our approach has reduced the overall computational cost

    Acetoacetate decarboxylase: hydrophobics, not electrostatics

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    Intermolecular interactions in the molecular ferromagnetic NH4Ni(mnt)(2)center dot H2O

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    Molecular solids that exhibit ferromagnetism are rare, and thus there is considerable interest in understanding the magnetic coupling mechanisms that operate in the few known examples(1). One such material is the charge-transfer salt NH4Ni(mnt)(2) . H2O, which consists of stacked planar metal ligands separated by ammonium cations. This salt is an insulator with localized spins that exhibit long-range ferromagnetic order at low temperatures (below 4.5 K)(2).3 Here we show that the Curie temperature demarcating the transition to the ferromagnetic state increases markedly with pressure until ferromagnetic order abruptly disappears at 6.8 kbar, indicating that the magnetic coupling is very sensitive to intermolecular separation. Using quantum-chemical calculations(3), we show that this pressure dependence arises from a competition between ferromagnetic coupling (resulting from nickel-sulphur intermolecular spin interactions), and antiferromagnetic coupling (from nickel-nickel interactions). We suggest that a similar interplay of spin-polarization effects might play a key role in determining the nature of the ground states (metallic, superconducting and so forth) observed in other molecular materials of this structural type(4,5)
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